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Contact Information:

Office:152F  Davey Lab, Phone:1-814-863-0090
Lab: S3/S4 Osmond Lab, Phone:1-814-863-0098
Email: liu@phys.psu.edu

Mailing Address:
Department of Physics
The Pennsylvania State University 
104 Davey Lab
University Park, PA 16802
USA
 

Last Updated:2-12-2009

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Spin-triplet, chiral p-wave superconductivity in Sr2RuO4

 

Most superconducting materials studied thus far, including high-Tc cuprates, are even-parity, spin-singlet (s- or d-wave) superconductors. Theoretical studies of systems where spin-triplet pairing may be realized, ranging from neutron stars to superconductor-ferromagnet nanostructures, have revealed exotic properties of these unconventional superconductors, raising the possibility of using them for novel applications. Until recently, superfluid 3He had long been considered the only established example of odd-parity pairing. However, work in our laboratory [1] has shown that odd-parity, spin-triplet pairing also occurs in Sr2RuO4 (strontium ruthenate), the only layered perovskite that becomes superconducting without the presence of Cu.

Our work on Sr2RuO4 has focused on tunneling and phase-sensitive measurements using high-quality single crystals grown by our collaborators. Our work on Pb-Sr2RuO4-Pb junctions revealed that superconductivity in Sr2RuO4 actually suppressed the Josephson coupling between two Pb electrodes, providing an early piece of evidence for unconventional, non-s-wave pairing in Sr2RuO4 [2]. We showed that the Josephson coupling between Sr2RuO4 and Indium was possible only along the in-plane direction [3], and demonstrated that the Andreev surface bound states exist in both the bulk and the 3K phases of Sr2RuO4 [4], further revealing the unconventional aspects of superconductivity in this material. We also imaged vortices in Sr2RuO4 in collaboration with other groups.

A phase-sensitive experiment provides the most stringent test on the pairing symmetry of a superconductor, as shown in the high-Tc work. In [1] we prepared Au0.5In0.5-Sr2RuO4 superconducting quantum interference devices (SQUIDs) and showed that the phase of the order parameter in Sr2RuO4 changes by pi under inversion.  Prior to this experiment, the constant spin susceptibility observed in the nuclear magnetic resonance Knight shift measurements was considered the strongest evidence for spin-triplet superconductivity in Sr2RuO4. However, reasons unrelated to pairing symmetry are also known to lead to constant spin susceptibility. For example, the Knight shift of vanadium, an s-wave superconductor, is unchanged across Tc. Our phase-sensitive work provided the first definitive experimental proof that Sr2RuO4 is an odd-parity superconductor, and will likely be the last push for Sr2RuO4 to find its way into textbooks.

We are currently doing experiments to clarify the exact form of the order parameter using phase-sensitive techniques, the possibility of d-vector rotation, and the existence and manipulation of domains and domain walls.

 

[1] K.D. Nelson, Z.Q. Mao, Y. Maeno, and Y. Liu, “Odd-parity superconductivity in Sr2RuO4,” Science 12, 1151-1154 (2004).

[2] R. Jin, Yu. Zadorozhny, Y. Liu, D.G. Schlom, Y. Mori, Y. Maeno, “Observation of anomalous temperature dependence of the critical current in Pb/ Sr2RuO4/Pb junctions,” Phys. Rev. B 59, 4433-4438 (1999)

[3] R. Jin, Y. Liu, Z.Q. Mao, and Y. Maeno, “Experimental observation of the selection rule in Josephson coupling between In and Sr2RuO4,” Europhys. Lett. 51, 341-347 (2000)

[4] Z.Q. Mao, K.D. Nelson, R.Jin, Y.Liu, and Y.Maeno, “Observation of Andreev surface bound states in the 3-K phase region of Sr2RuO4.,” Phys. Rev. Lett. 87, 037003 (2001)  

Contacts:

Ronald Myers, rjm31 @ psu.edu

Yiqun Alex Ying, yzy116 @ psu.edu

Neal Staley, nes151 @ psu.edu

 

 

 

 

 

 

Single Crystal of Sr2RuO4

Schematic of an Au0.5In0.5-Sr2RuO4 pi SQUID Phase-Sensitive Experiment

 Data confirming odd-parity superconductivity in Sr2RuO4